01. Universidade Federal Rural de Pernambuco - UFRPE (Sede)
URI permanente desta comunidadehttps://arandu.ufrpe.br/handle/123456789/1
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Resultados da Pesquisa
Item Aplicação da técnica de espectrometria de fluorescência de raios-x por dispersão de energia (EDXRF) para a quantificação de metais pesados em sedimentos de fundo(2025-02-26) Silva, Ingrid Coimbra da; Gomes, Maria José de Filgueiras; França, Elvis Joacir de; http://lattes.cnpq.br/1716496767364751; http://lattes.cnpq.br/0060810526769648; http://lattes.cnpq.br/9997365922939570Estudos recentes do monitoramento dos ecossistemas aquáticos retratam a relevância de tornarem os sedimentos de fundo como objeto de estudo dos impactos de contaminação ambiental por serem acumuladores, processadores e transportadores de metais pesados e espécies contaminantes. Nesse sentido, este presente estudo teve o objetivo de avaliar a aplicabilidade da técnica de Espectrometria de Fluorescência de Raios X por Dispersão de Energia (EDXRF) na quantificação dos elementos químicos Mn, Fe, Ni, Zn, Sr, Ti, Al, Si, K, Ca, V e La e avaliação da qualidade do sedimento a partir dos valores orientadores TEL e PEL de concentração estabelecidos pelo CCME (Canadian Council of Ministers of the Environment) e adotados pela CETESB para os elementos Ni e Zn como possíveis contaminantes em 52 amostras coletadas de 4 perfis de sedimentos originadas da Costa Brasileira, cedidos pela Pesquisa Desenvolvimento Inovação e Ensino (PDIE) ao Centro Regional de Ciências Nucleares do Nordeste (CRCN/NE). A natureza da pesquisa foi do tipo aplicada baseada em uma abordagem quantitativa através das médias aritméticas das concentrações dos metais pesados pelo EDX-720 e materiais de referências certificados (IAEA-SL-1) comparados com valores obtidos e certificados. O tratamento dos dados foi realizado mediante a metodologia de Fernández (2017) e o cálculo de incertezas analíticas com intervalo de 95% de confiança pela metodologia de Costa (2023). De maneira geral, o elemento Ni apresentou valores acima de TEL para a maioria dos pontos analisados, resultando na classificação de qualidade regular dos sedimentos analisados. O metal Zn esteve entre TEL e PEL para a maioria dos pontos coletados, sendo classificada a qualidade do sedimento como ótimo para esse elemento. As concentrações dos demais elementos não apresentam valores guias para comparação. Dessa forma, os objetivos deste trabalho foram atingidos e apresentaram relevância para a justificativa da aplicabilidade da técnica de EDXRF para o estudo de sedimentos de fundo e a importância da avaliação ambiental pela contaminação de metais pesados e seus impactos para os ecossistemas aquáticos causados pela ação antrópica ao longo dos anos.Item Potencial fitorremediador de Erythrina velutina Willd. cultivada em solo contaminado com cobre e incorporação de biocarvão(2022-10-04) Pundrich, Maria Gabriella Rodrigues; Freitas, Eliane Cristina Sampaio de; http://lattes.cnpq.br/7525975084334972; http://lattes.cnpq.br/2323613741603823In recent decades, researches have been demonstrating how heavy metals have the ability to stick and accumulate in the environment, being harmful to human health and the environment. Once the contamination of the soil happens, some actions are needed for the soil’s remediation.The objective of this reasearch was to evaluate the growth of the Erythrina velutina Willd seedlings cultivated in contaminated soil with copper and biochar. The first experiment was conducted for 21 days and the second for 69 days and analyzed the following morphological variables: Aerial Part Height (APH), Stem Diameter (SD), Aerial Part Increment (API) Stem Diameter Increment (SDI), Root’s Length (RL), Aerial Part Dry Mass (APDM), Root Dry mass (RDM), Total Dry Mass (TDM), Ratio between Aerial Part and Stem Diameter (AP/SD), Leaflet Numbers (LN), Leaflets Area (LA), Dickson Quality’s Index (DQI), Translocation Index (TI), Water Content in Aerial Part and Root (WCAPT) and Copper Concentrations in plant’s tissue (aerial and root part) through the EDS (energy dispersive spectroscopy).The collected data were submitted to a variance analysis (ANOVA) (p < 0,05) and Tukey test (p < 0,05). In the first experiment, it was observed that the biochar didn’t reveal any positive effect and didn’t benefit the growth of the seedlings. This result can be explained by the characteristics of biochar, influenced by the raw material and the carbonization process. In addition, the biochar could also have increased the cation exchange capacity and, consequentially, decreased Copper leach, enabling it to be more available to the seedlings. As for the second experiment, there was no significant difference of the 5% morphological variable of the seedlings, but it didn’t have Copper in the tissues analyzed, which could mean that the plant didn’t absolve as a result to a possible leach and/or an adsorption of the feedstock. Therefore, it is necessary complementary researches to evaluate the potential of Erythrina velutina Willd in projects of phytoremediation in soils contaminated by Copper.Item Aplicação da geoquímica inorgânica na investigação da contaminação ambiental de sedimentos do Rio Ipojuca, Caruaru/PE, Brasil(2021-07-15) Bezerra, Emanuelle da Silva; Santos, Jandyson Machado; http://lattes.cnpq.br/4137257750865101; http://lattes.cnpq.br/7596013067584452In the study about contamination of aquatic environments, the chemical characterization of sediments in the context of inorganic geochemistry with metal determination can provide important information, as the historic contamination of the aquatic ecosystem, leading to the knowledge of quantity, quality, period and effects caused by that contamination, most often from anthropic activities. The current study aims to achieve the quantification of metals by Inductively coupled plasma optical emission spectroscopy (ICP-OES) of sediments from the Rio Ipojuca, in the stretch of the municipality of Caruaru, state of Pernambuco, in order to identify the level of contamination through these elements, based on the values of the quality guide described on the resolution of CONAMA nº 454/2012. The values of Cr, Cu, Pb and Zn revealed that the sediments are with values higher than the limit value of the Level 1 quality's reference (VRQ1) for the most samples, which indicates that they are above the determined level from which there is less probability of adverse effects on the biota. Furthermore, for the concentration of Cr and Zn, two of the samples were found with concentrations higher than the limit value for the Level 2 quality's reference (VRQ2), leading to regions with values above the determined which there is a greater probability of adverse effects on the biota. In order to follow the resolution of CONAMA nº 454/2012, nine of the ten sediments studied fit the condition in which there is a need to carry out additional experiments, as ecotoxicity tests, due to the values above VRQ1 and VRQ2 indicate a potential contamination. Through the multivariate statistics analysis (PCA e HCA/heatmap) we have found a visualization that show a trend from less contaminated to more contaminated sediment, in which the most contaminated are located close to the urban centers of Caruaru City, pointing out that human activities are responsible for this environmental contamination. Thus, it is possible to conclude that there is a broader need for environmental monitoring of the Rio Ipojuca regarding heavy metal concentrations in the aquatic system, in a way that there is a continuous assessment of its quality and the harmful effects that the contamination may represent.